Czasopismo | OCHRONA PRZED KOROZJĄ | Rocznik 2024 - zeszyt 8

Application of heteropoly compounds with Keggin structure in corrosion protection and Ni-MH cell technology

Zastosowanie heteropolizwiązków o strukturze Keggina w ochronie przed korozją i technologii ogniw Ni-MH

10.15199/40.2024.8.1

nr katalogowy: 149807
10.15199/40.2024.8.1

Streszczenie

Heteropolikwasy (HPK) i ich sole to grupa związków chemicznych, która ze względu na różnorodność właściwości i zastosowań wzbudza zainteresowanie wielu badaczy. Związki te charakteryzują się między innymi wysoką mocą i ruchliwością protonów, a także zdolnością do przyjmowania i uwalniania elektronów. HPK są badane zwłaszcza pod kątem projektowania różnych katalizatorów funkcjonalnych. Zakres ich zastosowania stale się zwiększa ze względu na możliwość modyfikacji ich składu chemicznego. W pracy zostały opisane podstawowe obszary badań heteropoli związków (HPZ) o strukturze Keggina. Uwzględniono ich właściwo ści katalityczne i antykorozyjne w celu dokonania oceny możliwości wykorzystania HPK w technologii ogniw Ni-MH. Analiza literatury przedmiotu potwierdziła założenie, że związki te mają duży potencjał aplikacyjny i stanowią interesujący przedmiot badań zarówno dla chemików, jak i materiałoznawców. Z publikacji dotyczących tego za gadnienia wynika, że HPK powinny spełniać dwa ważne zadania: ka talizować procesy ładowania i rozładowania elektrod wodorkowych w ogniwach Ni-MH oraz inhibitować procesy korozyjne, prowadzące do degradacji materiału elektrodowego.

Abstract

Heteropolyacids (HPA) and their salts are a group of chemical compounds that arouse the interest of many researchers due to the variety of properties and applications. These compounds are characterized by, among other things, high proton mobility, as well as the ability to accept and release electrons. HPAs are extensively studied especially in the design of various functional catalysts. The area of their application is constantly growing due to the possibility of modifying their chemical composition. This work presents the basic areas of research on Keggin-type heteropoly compounds (HPC), with particular emphasis on their catalytic and anti-corrosion properties, to assess the possibility of using HPAs in Ni-MH cell technology. Analysis of the available literature confirmed our assumption that these are promising compounds offering both chemists and materials scientists many cognitive and application possibilities. Literature examples indicate that HPA should fulfil two important tasks: catalyse the charging/discharging processes of hydride electrodes in Ni-MH cells and inhibit corrosion processes leading to the degradation of the electrode material.

Słowa kluczowe

Keywords

Bibliografia

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