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Improving mechanical and thermal properties of unsaturated polyester resin by adding automotive glass waste

Poprawa właściwości mechanicznych i termicznych nienasyconej żywicy poliestrowej poprzez dodanie szklanych odpadów przemysłu motoryzacyjnego

10.15199/40.2024.10.2

nr katalogowy: 150983
10.15199/40.2024.10.2

Streszczenie

The primary goal of this study was to improve a number of mechanical properties of UPE (unsaturated polyester) by using available and cheap particulate fillers, such as reinforcement with powder with a particle size of 75 μm. A composite of UPE with automotive glass waste (as filler materials) was prepared, and some mechanical and thermal properties were studied at certain weight percentages (5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, and 50%). A comparison was made between the polymeric composites before and after the process of reinforcing them with waste automotive glass, and it was found that with a 30% content of these additives they showed good mechanical properties. These additions were made at different temperatures: 8°C, 25°C and 50°C. The results before and after the reinforcement process for polymer composites showed that there was an improvement in the mechanical properties (compressive strength, hardness and impact resistance) with a decrease in the modulus of elasticity (Young’s modulus). When processing was carried out at a temperature of 8°C, a decrease in the values of the mechanical properties (compressive strength, impact strength, modulus of elasticity, thermal conductivity) was observed in varying proportions, with an increase in the values of hardness. Conversely, when the samples were heated to a temperature of 50°C, there was an increase in the values of the above-mentioned properties and a significant decrease in the hardness values. Throughout the research, various measurement techniques were used, including scanning electron microscopy (SEM), infrared spectroscopy (IR) and thermogravimetric analysis (TGA). Their purpose was to monitor the changes that occurred in the polymer as a result of the use of the reinforcing material (automotive glass).

Abstract

Głównym celem badań było poprawienie właściwości mechanicznych UPE (nienasyconego poliestru) poprzez zastosowanie dostępnych i ta nich wypełniaczy cząsteczkowych, na przykład przez wzmocnienie proszkiem o wielkości cząstek wynoszącej 75 μm. Przygotowano kom pozyt UPE ze szklanymi odpadami przemysłu motoryzacyjnego (jako materiałem wypełniającym) i zbadano wybrane właściwości mecha niczne i termiczne przy określonych procentach wagowych (5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45% i 50%). Porównano kompozyty polimerowe przed procesem wzmacniania odpadami szklanymi i po nim. Stwierdzono, że przy 30-procentowym udziale tych dodatków wy kazywały one dobre właściwości mechaniczne. Dodatki zostały wpro wadzone w różnych temperaturach: 8°C, 25°C i 50°C. Analiza wyników przed wzmocnieniem kompozytów polimerowych i po tym procesie wykazała, że nastąpiła poprawa właściwości mechanicznych (wytrzy małości na ściskanie, twardości i udarności) przy spadku modułu sprę żystości (modułu Younga). Po przetwarzaniu w temperaturze 8°C odno towano spadek wartości parametrów mechanicznych (wytrzymałości na ściskanie, udarności, modułu sprężystości, przewodności cieplnej) w różnych proporcjach przy jednoczesnym wzroście twardości. Z kolei po podgrzaniu próbek do temperatury 50°C zwiększyły się wartości wy mienionych właściwości i znacznie zmniejszyła twardość. W badaniach wykorzystano różne techniki pomiarowe, w tym skaningową mikrosko pię elektronową (SEM), spektroskopię w podczerwieni (IR) i analizę ter mograwimetryczną (TGA), w celu zweryfikowania zmian zachodzących w polimerze w wyniku zastosowania materiału wzmacniającego (szkla nych odpadów przemysłu motoryzacyjnego).

Słowa kluczowe

Keywords

Bibliografia

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