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Applicability of microwave plasma CVD and electrochemical process for deposition of diamond-related thin films

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Diamond is absolutely unique among solid crystals because of its outstanding properties, such as: high thermal conductivity at room temperature, high electrical resistivity, transparency, refraction index and hardness, wide band-gap, and many others. Unfortunately, there is still a gap between potential applicability and actual usage of diamond-based devices. In fact, synthetic single-crystalline diamonds are still too expensive, whereas diamond films discussed in the paper exhibit polycrystalline structure so that their properties are significantly worse with respect to pure gemstones. In order to explore the aforementioned potential, a large variety of methods of diamond deposition has been developed for the last two decades, including for instance: chemical vapor deposition[...]

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